A photocatalytic method for the generation of the 1,1,1,3,3,3-hexafluoroisopropyl radical-Reference-Cited by-同舟云学术

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A photocatalytic method for the generation of the 1,1,1,3,3,3-hexafluoroisopropyl radical

Published:2024 Issue:17 Volume:11 Page:4762-4768
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lunkov Sergey S.¹,Kostromitin Vladislav S.¹²,Zemtsov Artem A.¹,Levin Vitalij V.¹^ORCID,Dilman Alexander D.¹^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

2. Lomonosov Moscow State University, Department of Chemistry, 119991 Moscow, Leninskie Gory 1-3, Russian Federation

Abstract

A method for the generation of the hexafluoroisopropyl radical by photoredox cleavage of the C,O bond is described. The key reagent is obtained from hexafluoroisopropanol.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO01023J

Reference58 articles.

1. Introduction of Fluorine and Fluorine-Containing Functional Groups

2. P.Beier , M.Zibinsky and G. K. S.Prakash , Nucleophilic Additions of Perfluoroalkyl Groups , in Org. React. , John Wiley & Sons, Inc. , 2017 , vol. 91 , p. 792

3. G. K. S.Prakash and Z.Zhang , New Nucleophilic Fluoroalkylations , in Modern Synthesis Processes and Reactivity of Fluorinated Compounds , ed. H. Groult , F. R. Leroux and A. Tressaud , Elsevier , Amsterdam , 2017 , pp. 289–337 . 10.1016/B978-0-12-803740-9.00011-1

4. Radical Fluoroalkylation Reactions

5. Radical Perfluoroalkylation of Aliphatic Substrates

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