Reactions of (Ph)tBuP-P(SiMe3)Li·3THF with [(PNP)TiCl2] and [MeNacNacTiCl2·THF]: synthesis of first PNP titanium(iv) complex with the phosphanylphosphinidene ligand [(PNP)Ti(Cl){η2-P-P(Ph)tBu}]-Reference-Cited by-同舟云学术

Reactions of (Ph)tBuP-P(SiMe3)Li·3THF with [(PNP)TiCl2] and [MeNacNacTiCl2·THF]: synthesis of first PNP titanium(iv) complex with the phosphanylphosphinidene ligand [(PNP)Ti(Cl){η2-P-P(Ph)tBu}]

Published:2018 Issue:29 Volume:47 Page:9733-9741
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ziółkowska Aleksandra¹²³⁴⁵,Szynkiewicz Natalia¹²³⁴⁵^ORCID,Wiśniewska Aleksandra¹²³⁴⁵^ORCID,Pikies Jerzy¹²³⁴⁵,Ponikiewski Łukasz¹²³⁴⁵^ORCID

Affiliation:

1. Gdansk University of Technology

2. Faculty of Chemistry

3. Department of Inorganic Chemistry

4. 80-233 Gdansk

5. Poland

Abstract

We present the reactivity of [(PNP)TiCl₂] and [^MeNacNacTiCl₂·THF] towards the lithium derivative of diphosphane (Ph)tBuP-P(SiMe₃)Li·nTHF.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01833B

Reference27 articles.

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2. Titanium carbene complexes as useful tools in organic synthesis

3. Titanium carbenoid reagents for converting carbonyl groups into alkenes

4. Metallo-Wittig chemistry of an alkylidene to form a terminal titanium oxo complex

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