Activation of the CP bond in phosphanylphosphaalkenes (CP–P bond system) in the reaction with nucleophilic reagents: MeLi, <i>n</i>BuLi and <i>t</i>BuLi-Reference-Cited by-同舟云学术

Activation of the CP bond in phosphanylphosphaalkenes (CP–P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi

Published:2022 Issue:18 Volume:12 Page:10989-10996
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ziółkowska Aleksandra¹^ORCID,Szynkiewicz Natalia¹^ORCID,Ponikiewski Łukasz¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Technology, Gabriela Narutowicza Str. 11/12, 80-233 Gdansk, Poland

Abstract

The performed reactions of (biph)(H)CP–PtBu2 with MeLi, nBuLi lead to substitution of two organic groups on the P-atom and to cleavage of the P–P bond, respectively. In the case of tBuLi, only one group is substituted with reminded P–P bond.

Funder

Politechnika Gdańska

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D1RA09215D

Reference41 articles.

1. Phosphinidene Transfer Reactions of the Terminal Phosphinidene Complex Cp2Zr(:PC6H2-2,4,6-t-Bu3)(PMe3)

2. The "phospha-Wittig" reaction: a new method for building phosphorus-carbon double and single bonds from carbonyl compounds

3. Scope and Limitations of the Base-Catalyzed Phospha-Peterson PC Bond-Forming Reaction

4. A Convenient Synthesis of New Isolable Phosphaalkenes Using the Base-Induced Rearrangement of Secondary Vinylphosphines

5. Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

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