From phosphanylphosphaalkenes to coordination copper and silver polymers containing P

From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds

Published:2024 Issue:22 Volume:53 Page:9350-9357
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ziółkowska Aleksandra¹^ORCID,Prześniak-Welenc Marta²^ORCID,Kruczyński Tomasz³,Gamer Michael⁴,Ponikiewski Łukasz¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry, Chemical Faculty, Gdansk University of Technology, Narutowicza Str. 11/12, 80-233 Gdansk, Poland

2. Institute of Nanotechnology and Materials Engineering, Gdansk University of Technology, Narutowicza Str. 11/12, 80-233 Gdansk, Poland

3. Department of Chemistry and Biochemistry, College of Science and Mathematics, Kennesaw State University, 1000 Chastain Road, Kennesaw GA 30144, USA

4. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany

Abstract

Reactions of Ph2CP-PtBu2 with aromatic or aliphatic dithiols lead to the activation of the PC bond by a 1,2-addition reaction mechanism. Addition of copper or silver chloride, in the next step, leads to organometallic polymers with P–P bonds.

Funder

Politechnika Gdańska

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00987H

Reference56 articles.

1. Phosphinine-based ligands: Recent developments in coordination chemistry and applications

2. Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems

3. Bonding and energetics of phosphorus (III) ligands in transition metal complexes

4. The electron influence of substituents containing trivalent phosphorus

5. Phospholenes from Phosphabenzenes by Selective Ring Contraction