Experimental and theoretical investigation of the reactivity of [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2}] towards selected ketones-Reference-Cited by-同舟云学术

Experimental and theoretical investigation of the reactivity of [(BDI*)Ti(Cl){η2-P(SiMe3)-PiPr2}] towards selected ketones

Published:2021 Issue:4 Volume:50 Page:1390-1401
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ziółkowska Aleksandra¹²³⁴⁵^ORCID,Szynkiewicz Natalia¹²³⁴⁵^ORCID,Ponikiewski Łukasz¹²³⁴⁵^ORCID

Affiliation:

1. Gdansk University of Technology

2. Faculty of Chemistry

3. Department of Inorganic Chemistry

4. 80-233 Gdansk

5. Poland

Abstract

Reaction of [(BDI*)Ti(Cl){η²-P(SiMe₃)-PiPr₂}] with acetone led to new titanium complexes with a C–P–P bond by insertion of one molecule of acetone into two different Ti–P bonds (involving the phosphanyl phosphorus and the phosphido phosphorus atom).

Funder

Politechnika Gdańska

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04014B

Reference83 articles.

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