Ruthenium mediated halogenation of white phosphorus: synthesis and reactivity of the unprecedented P4Cl2 moiety-Reference-Cited by-同舟云学术

Ruthenium mediated halogenation of white phosphorus: synthesis and reactivity of the unprecedented P4Cl2 moiety

Published:2019 Issue:11 Volume:48 Page:3593-3600
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bispinghoff Mark¹²³⁴^ORCID,Benkő Zoltán⁵⁶⁷,Grützmacher Hansjörg¹²³⁴^ORCID,Calvo Fuencisla Delgado⁸⁹¹⁰^ORCID,Caporali Maria⁸⁹¹⁰^ORCID,Peruzzini Maurizio⁸⁹¹⁰^ORCID

Affiliation:

1. Laboratory of Inorganic Chemistry

2. ETH Zürich

3. 8093 Zürich

4. Switzerland

5. Budapest University of Technology and Economics

6. H-1111 Budapest

7. Hungary

8. CNR ICCOM

9. 50019 Sesto Fiorentino

10. Italy

Abstract

P₄ inserts into the Ru–Cl bond of [RuCl(Cp*)(PCy₃)], yielding the unprecedented P₄Cl₂ moiety which can be selectively alkylated to [P₄ⁿBu₂].

Funder

H2020 Marie Skłodowska-Curie Actions

Nemzeti Kutatási, Fejlesztési és Innovációs Hivatal

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT01840E

Reference31 articles.

1. D. E. C. Corbridge , Phosphorus, an Outline of its Chemistry, Biochemistry and Technology , Elsevier , Amsterdam , 5th edn., 1995

2. P4 Activation by Late-Transition Metal Complexes

3. Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

4. Coordination chemistry and functionalization of white phosphorus via transition metal complexes

5. Functionalization of white phosphorus in the coordination sphere of transition metal complexes

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