A computational mechanistic investigation of hydrogen production in water using the [RhIII(dmbpy)2Cl2]+/[RuII(bpy)3]2+/ascorbic acid photocatalytic system-Reference-Cited by-同舟云学术

A computational mechanistic investigation of hydrogen production in water using the [RhIII(dmbpy)2Cl2]+/[RuII(bpy)3]2+/ascorbic acid photocatalytic system

Published:2015 Issue:16 Volume:17 Page:10497-10509
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kayanuma Megumi¹²³⁴⁵,Stoll Thibaut⁶⁷⁸⁵⁹,Daniel Chantal¹²³⁴⁵,Odobel Fabrice¹⁰¹¹¹²¹³¹⁴,Fortage Jérôme⁶⁷⁸⁵⁹,Deronzier Alain⁶⁷⁸⁵⁹,Collomb Marie-Noëlle⁶⁷⁸⁵⁹

Affiliation:

1. Laboratoire de Chimie Quantique

2. Institut de Chimie Strasbourg

3. UMR 7177 CNRS/UdS

4. 67037 Strasbourg

5. France

6. Univ. Grenoble Alpes

7. DCM

8. F-38000 Grenoble

9. CNRS

10. UMR 6230

11. Chimie et Interdisciplinarité

12. Synthèse

13. Analyse

14. Modélisation – CEISAM

Abstract

The involvement of the Rh^III(H) and Rh^II(H) hydride species in the mechanism of H₂ production could explain the high efficiency of the photocatalytic system.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP04949G

Reference84 articles.

1. The Future of Energy Supply: Challenges and Opportunities

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5. The Hydrogen Issue

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