A huge novel polyoxometalate-based cluster Fe10P4W32 exhibiting prominent electrocatalytic activity for the oxygen evolution reaction and third-order NLO properties
Author:
Affiliation:
1. College of Chemical Engineering
2. State Key Laboratory of Materials-Oriented Chemical Engineering
3. Nanjing Tech University
4. Nanjing 210009
5. P. R. China
6. School of Chemistry and Chemical Engineering
7. Liaoning Normal University
Abstract
A novel high-nuclear POM-based cluster {Fe10P4W32} consists of two inorganic blocks {P2W14} and four organic groups linked by ten iron ions.
Funder
National Natural Science Foundation of China
Priority Academic Program Development of Jiangsu Higher Education Institutions
Natural Science Research of Jiangsu Higher Education Institutions of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC03937F
Reference45 articles.
1. A Series of Banana-Shaped 3d-4f Heterometallic Cluster Substituted Polyoxometalates: Syntheses, Crystal Structures, and Magnetic Properties
2. Elimination-Fusion Self-Assembly of a Nanometer-Scale 72-Nucleus Silver Cluster Caging a Pair of [EuW10 O36 ]9− Polyoxometalates
3. An unprecedented {Ni14SiW9} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity
4. Octahedron-shaped three-shell Ln14-substituted polyoxotungstogermanates encapsulating a W4O15 cluster: luminescence and frequency dependent magnetic properties
5. Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)
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