A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO<sub>2</sub>-Reference-Cited by-同舟云学术

A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO₂

Published:2024 Issue:17 Volume:53 Page:7257-7262
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhu Yinhua¹,Yan Pinfang¹,Xu Lingtong¹,Du Zeyu¹,Mei Hua¹,Xu Yan¹^ORCID

Affiliation:

1. College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, P. R. China

Abstract

An innovative polyoxometalate-based cobalt-modified organophosphate framework was synthesized and applied for CO2 reduction for a high selectivity of 94.5% and an ultra-high CO production rate of 13 676 μmol g−1h−1 in photocatalytic investigations.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00812J

Reference40 articles.

1. Coupling carbon dioxide reduction with water oxidation in nanoscale photocatalytic assemblies

2. Polyoxometalate-Based Metal–Organic Frameworks with Unique High-Nuclearity Water Clusters

3. Enhancing the durability of Au clusters in CO₂photoreductionviaencapsulation in Cu-based metal–organic frameworks

4. Ultrasmall C-TiO2−x nanoparticle/g-C3N4 composite for CO2 photoreduction with high efficiency and selectivity

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