Enhancing the durability of Au clusters in CO2photoreductionviaencapsulation in Cu-based metal–organic frameworks

Author:

Zhang Jun1,Cui Xiaofeng12,Zhou Yu2,Kong Tingting1,Wang Yixin1,Wei Xianwen1ORCID,Xiong Yujie13ORCID

Affiliation:

1. Anhui Engineering Research Center of Carbon Neutrality, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, Anhui, P. R. China

2. School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246011, Anhui, P. R. China

3. School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, 230026, Anhui, P. R. China

Abstract

The encapsulation of Au25nanoclusters in Cu3(BTC)2metal–organic frameworks can achieve CO2photoreduction for selective CO production in a gas–solid reaction system with remarkably enhanced durability.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Anhui Province

Excellent Young Talents Fund Program of Higher Education Institutions of Anhui Province

Natural Science Foundation of Shaanxi Provincial Department of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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