Interconversion of CN and CNH2ligands: electrosynthesis and X-ray crystallographic structures of trans-[W(CNH2)Cl(dppe)2] and trans-[W(CNH2)Cl(dppe)2][BF4](dppe = Ph2PCH2CH2PPh2): aminocarbyne (C–NH2) or iminomethylenium (CNH2+) ligands?
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1994/C3/C39940000425
Reference9 articles.
1. Electroreduction of co-ordinated cyanide to the aminocarbyne ligand (CNH2) and a pathway for isomerisation of ligating methyleneamide (NCH2): reactions at molybdenum of relevance to cyanide reduction by nitrogenase
2. Transformation of a methyleneamide ligand at molybdenum: electrochemical oxidation to a cyanide, reactions with elemental oxygen, sulphur or selenium and X-ray crystal structures of trans-[Mo(CN)Cl(dppe)2]·MeOH and trans-[Mo(NCS)Cl(dppe)2]; electroreduction of the cyanide to an aminocarbyne, trans-[Mo(CNH2)Cl(dppe)2](dppe = Ph2PCH2CH2PPh2)
3. Structural and electronic comparison of 15- to 17-electron dichloro-complexes of molybdenum and rhenium: electrochemical behaviour and crystal structures of trans-[ReCl2(dppe)2]A (A = Cl or BF4; dppe = Ph2PCH2CH2PPh2), trans-[ReCl2(dppe)2] and [NBun4]2[trans-MoCl2(dppe)2][BF4]3
4. Diazoalkane complexes of molybdenum and tungsten via hydrazido(2–) complexes
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