EPR detection and characterisation of a paramagnetic Mo(iii) dihydride intermediate involved in electrocatalytic hydrogen evolution
Author:
Affiliation:
1. Energy Materials Laboratory
2. School of Chemistry
3. University of East Anglia
4. Norwich NR4 7TJ
5. UK
Abstract
EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(iv) acetato dihydride are a consequence of an η2–η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(iii) dihydride.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04432D
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