Reactions of the unsaturated alkyne cluster [Os3(CO)7{µ3-η2(⊥)-PhC2Ph}(dppm)] with P-donors; crystal structures of [Os3(CO)6(PhC2Ph)(dppm){P(OMe)3}] and two isomers of [Os3(CO)7(PhC2Ph)(dppm)(PBu3)](dppm = Ph2PCH2PPh2)-Reference-Cited by-同舟云学术

Reactions of the unsaturated alkyne cluster [Os3(CO)7{µ3-η2(⊥)-PhC2Ph}(dppm)] with P-donors; crystal structures of [Os3(CO)6(PhC2Ph)(dppm){P(OMe)3}] and two isomers of [Os3(CO)7(PhC2Ph)(dppm)(PBu3)](dppm = Ph2PCH2PPh2)

Published:1996 Issue:1 Volume: Page:117-123
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Harding Rachel A.,Smith Anthony K.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1996/DT/DT9960000117

Reference9 articles.

1. Alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt and nickel triads

2. D. Osella and P. R.Raithby, in Stereochemistry of Organometallic and Inorganic Compounds, ed. I. Bernal, Elsevier, Amsterdam, 1988, vol. 3.

3. Electronic control of the co-ordination mode of an alkyne to a trimetallic cluster; X-ray crystal structure of Os3(CO)7(µ3-η2(⊥)-PhCCPh)(Ph2PCH2PPh2)

4. Reactions of the co-ordinatively unsaturated cluster [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] with alkynes RCCR (R = Ph, C6H4Me, Me or CF3); crystal structures of [Os3(CO)8{µ3–η2(∥)–RC2R}(Ph2PCH2PPh2)](R = Me or CF3) and electrochemical behaviour of triosmium–alkyne clusters

5. Reaction of the unsaturated triosmium clusters [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}] and [Os3H(CO)8{Ph2PC(CH2)P(Ph)C6H4}] with phosphines and phosphites; crystal structures of [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}(PPri3)], [Os3(CO)8(Ph2PCH2PPh2){P(OMe)3}2], and [Os3(CO)8(Ph2PCH2PPh2)(PPh3)2]

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