Reactions of the co-ordinatively unsaturated cluster [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] with alkynes RCCR (R = Ph, C6H4Me, Me or CF3); crystal structures of [Os3(CO)8{µ3–η2(∥)–RC2R}(Ph2PCH2PPh2)](R = Me or CF3) and electrochemical behaviour of triosmium

Reactions of the co-ordinatively unsaturated cluster [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] with alkynes RCCR (R = Ph, C6H4Me, Me or CF3); crystal structures of [Os3(CO)8{µ3–η2(∥)–RC2R}(Ph2PCH2PPh2)](R = Me or CF3) and electrochemical behaviour of triosmium–alkyne clusters

Published:1993 Issue:6 Volume: Page:827-834
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Brown Michael P.,Dolby P. Ann,Harding Marjorie M.,Mathews A. Jane,Smith Anthony K.,Osella Domenico,Arbrun Mauro,Gobetto Roberto,Raithby Paul R.,Zanello Piero

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930000827

Reference35 articles.

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3. Structure of and Bonding in an Alkyne-Nonacarbonyltriiron Complex. A New Type of Iron-Acetylene Interaction

4. The alkyne-cluster interaction: structural, theoretical and mechanistic studies on the M2M'(CO)9(.mu.3-.eta.2-alkyne) complex (M = Fe; M' = Fe and Ru)

5. Reaction of Os3(CO)9(C2Ph2) with diazomethane. Photoinduced loss of dinitrogen and thermally activated coupling of methylene and diphenylacetylene on the triosmium framework

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