Reaction of the unsaturated triosmium clusters [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}] and [Os3H(CO)8{Ph2PC(CH2)P(Ph)C6H4}] with phosphines and phosphites; crystal structures of [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}(PPri3)], [Os3(CO)8(Ph2PCH2PPh2){P(OMe)3}2], and [Os3(CO)8(Ph2PCH2PPh2)(PPh3)2]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930001671
Reference22 articles.
1. The high yield synthesis of an unsaturated osmium cluster; the X-ray crystal structure of [Os3(CO)8(H){Ph2PCH2P(Ph)C6H4}]
2. Reaction between [Ru3(CO)12] and the tridentate phosphine ligand HC(PPh2)3; X-ray crystal structures of complexes [Ru3(CO)9{Ph2PCHP(Ph)C6H4PPh}], [Ru2H(CO)4(Ph2PCHPPh2){PhPC6H4C(O)}], and [Ru2(CO)4Cl(PPh2)(dppm)]
3. Reactions of the co-ordinatively unsaturated cluster [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] with alkynes RCCR (R = Ph, C6H4Me, Me or CF3); crystal structures of [Os3(CO)8{µ3–η2(∥)–RC2R}(Ph2PCH2PPh2)](R = Me or CF3) and electrochemical behaviour of triosmium–alkyne clusters
4. Trinuclear osmium clusters containing bidentate Ph2PCH2PPh2 and Me2PCH2PMe2 ligands: X-ray crystal structures of the complexes [Os3H(CO)9(Me2PCHPMe2)] and [Os3H(OH)(CO)8(Ph2PCH2PPh2)]
5. Transformation of the bis(diphenylphosphino)methane ligand on the triruthenium nonacarbonyl framework. Synthesis and characterization of the ruthenium complexes Ru3(CO)9(.mu.3-.eta.3-P(C6H5)CH2P(C6H5)(C6H4)), Ru3(CO)9(.mu.-H)(.mu.3-.eta.2-P(C6H5)CH2P(C6H5)2), and Ru3(CO)10(.mu.-.eta.2-P(C6H5)CH2P(C6H5)(C6H4))
Cited by 36 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Triosmium Carbonyl Clusters Containing a Mixture of Dppm and Dppe Ligands;Journal of Chemical Crystallography;2020-10-31
2. Reactions of the lightly-stabilized triosmium cluster Os3(CO)8{μ3-Ph2PCH(Me)P(Ph)C6H4}(μ-H) with two-electron donor ligands;Polyhedron;2020-08
3. Double activation of the diphosphinite pincer proligand by a triosmium carbonyl cluster;Mendeleev Communications;2020-05
4. Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 (μ-dppm)(μ-H) 2 and Os 3 (CO) 8 (μ-dppf)(μ-H) 2 with activated alkynes;Journal of Organometallic Chemistry;2017-05
5. A comparative study of the reactivity of the lightly stabilized cluster [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] towards tri(2-thienyl)-, tri(2-furyl)- and triphenyl-phosphine;Journal of Organometallic Chemistry;2014-02
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