Stereoselective formation and catalytic activity of hydrido(acylphosphane)(chlorido)(pyrazole)rhodium(iii) complexes. Experimental and DFT studies-Reference-Cited by-同舟云学术

Stereoselective formation and catalytic activity of hydrido(acylphosphane)(chlorido)(pyrazole)rhodium(iii) complexes. Experimental and DFT studies

Published:2015 Issue:29 Volume:44 Page:13141-13155
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

San Nacianceno Virginia¹²³⁴,Azpeitia Susan¹²³⁴,Ibarlucea Lourdes¹²³⁴,Mendicute-Fierro Claudio¹²³⁴,Rodríguez-Diéguez Antonio⁵⁶⁴,Seco José M.¹²³⁴,San Sebastian Eider¹²³⁴,Garralda María A.¹²³⁴

Affiliation:

1. Facultad de Química de San Sebastián

2. Universidad del País Vasco (UPV/EHU)

3. 20080 San Sebastián

4. Spain

5. Facultad de Ciencias. Universidad de Granada

6. 18071 Granada

Abstract

Stereoselectivity assisted by hydrogen bond formation, inhibited by steric hindrance, predicted by DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01705J

Reference109 articles.

1. Scope and Mechanism of the Intermolecular Addition of Aromatic Aldehydes to Olefins Catalyzed by Rh(I) Olefin Complexes

2. Rh-Catalyzed Carbonyl Hydroacylation: An Enantioselective Approach to Lactones

3. Ruthenium Hydride-Catalyzed Addition of Aldehydes to Dienes Leading to β,γ-Unsaturated Ketones

4. Intermolecular Alkene and Alkyne Hydroacylation with β-S-Substituted Aldehydes: Mechanistic Insight into the Role of a Hemilabile P-O-P Ligand

5. Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination

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