Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
Author:
Affiliation:
1. Department of Chemistry, Inorganic Chemistry Laboratories, South Parks Road, University of Oxford, Oxford, U.K. OX1 3QR
2. School of Chemistry, University of Bristol, Cantocks Close, Bristol, U.K. BS8 1TS
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om300647n
Reference65 articles.
1. Isolation of a stable acylrhodium(III) hydride intermediate formed during aldehyde decarbonylation. Hydroacylation
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3. Catalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistance
4. Homogeneous catalysis. Mechanism of catalytic hydroacylation: the conversion of 4-pentenals to cyclopentanones
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