Slow magnetic relaxation in a dimeric Mn2Ca2 complex enabled by the large Mn(iii) rhombicity-Reference-Cited by-同舟云学术

Slow magnetic relaxation in a dimeric Mn2Ca2 complex enabled by the large Mn(iii) rhombicity

Published:2017 Issue:3 Volume:46 Page:720-732
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Arauzo Ana¹²³⁴^ORCID,Bartolomé Elena⁵⁶⁴,Benniston Andrew C.⁷⁸⁹¹⁰¹¹,Melnic Silvia¹²¹³¹⁴¹⁵,Shova Sergiu¹⁶¹⁷¹⁸,Luzón Javier¹⁹²⁰²¹⁴²²,Alonso Pablo J.²²²³³⁴^ORCID,Barra Anne-Laure²⁴²⁵²⁶²⁷,Bartolomé Juan²²²³³⁴

Affiliation:

1. Servicio de Medidas Físicas

2. Universidad de Zaragoza

3. 50009 Zaragoza

4. Spain

5. Escola Universitària Salesiana de Sarrià (EUSS)

6. 08017 Barcelona

7. Molecular Photonics Laboratory

8. School of Chemistry

9. Newcastle University

10. Newcastle-upon-Tyne

11. UK

12. Institute of Chemistry

13. Academy of Sciences of Moldova

14. Chisinau

15. Moldova

16. Institute of Macromolecular Chemistry “Petru Poni” Iasi

17. 700487 Iasi

18. Romania

19. Centro Universitario de la Defensa

20. Academia General Militar

21. Zaragoza

22. Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada

23. CSIC-Universidad de Zaragoza

24. Laboratoire National des Champs Magnétiques Intenses

25. CNRS and Université Grenoble Alpes

26. 38042 Grenoble Cedex 9

27. France

Abstract

A large single-ion transverse anisotropy at Mn(iii) sites induces slow magnetic relaxation at zero magnetic field of the ferromagnetic Mn dimers in a singular Mn₂Ca₂ complex.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT02509A

Reference73 articles.

1. Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry

2. Synthesis of 3d Metallic Single-Molecule Magnets

3. Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground State

4. Photosynthetic water oxidation

5. Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen

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