Structural, optical and magnetic properties of a new metal–organic CoII-based complex

Author:

Jabeur Wiem1,Korb Marcus2ORCID,Hamdi Mohamed3ORCID,Holub Mariia4ORCID,Princík Dávid5,Zeleňák Vladimír5ORCID,Sanchez-Coronilla Antonio6ORCID,Shalash Marwan3,Čižmár Erik4ORCID,Naïli Houcine1

Affiliation:

1. Laboratory Physico Chemistry of the Solid State, Department of Chemistry, Faculty of Sciences of Sfax, Sfax University, POBOX 1171, 3000 Sfax, Tunisia

2. The University of Western Australia, School of Molecular Sciences, 35 Stirling Highway, Crawley, Perth, Western Australia 6009, Australia

3. Department of Chemistry, College of Sciences and Arts Turaif, Northern Border University, Arar, Saudi Arabia

4. Institute of Physics, Faculty of Science, P. J. Šafárik University in Košice, SK-041 54 Košice, Slovakia

5. Department of Inorganic Chemistry, Faculty of Science, P. J. Šafárik University, Košice SK-041 54, Slovakia

6. Departamento de Química Física, Facultad de Farmacia, Universidad de Sevilla, E-41012 Sevilla, Spain

Abstract

A new semiconducting compound [C5H8N3]2[CoCl4(C5H7N3)2] displays HF and LF relaxation channels, characterized by under-barrier and direct relaxation processes, respectively, as revealed by ab initio calculations and magnetic data analysis.

Funder

Northern Border University

Agentúra na Podporu Výskumu a Vývoja

Junta de Andalucía

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

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