Ambipolar charge-trapping in self-assembled nanostructures of a supramolecular miktoarm star-shaped copolymer with a zinc phthalocyanine core

Author:

Zhong Xinhao12,Panigrahi Debdatta3ORCID,Hayakawa Ryoma3ORCID,Wakayama Yutaka3ORCID,Harano Koji4ORCID,Takeuchi Masayuki12ORCID,Aimi Junko1ORCID

Affiliation:

1. Research Center for Macromolecules and Biomaterials, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

2. Department of Materials Science and Engineering, Faculty of Pure & Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan

3. Research Center for Materials Nanoarchitectonics (MANA), NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

4. Center for Basic Research on Materials, NIMS, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

Abstract

Supramolecular miktoarm star-shaped copolymers with a zinc phthalocyanine core exhibit phase-separated nanostructures that enhance ambipolar charge-trapping capabilities in the organic field-effect transistor memory devices.

Funder

Izumi Science and Technology Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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