Tuning the magnetic behaviors in [FeIII12LnIII4] clusters with aromatic carboxylate ligands

Author:

Liu Sui-Jun1234,Zeng Yong-Fei1234,Xue Li1234,Han Song-De1234,Jia Ji-Min1234,Hu Tong-Liang1234,Bu Xian-He1234

Affiliation:

1. Department of Chemistry

2. TKL of Metal- and Molecule-Based Material Chemistry and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

3. Nankai University

4. Tianjin 300071, P.R. China

Abstract

Six new Fe–Ln clusters composed of a Fe12Ln4 core derived from two monocarboxylate ligands have been successfully obtained with a step-by-step strategy. Magnetic analyses suggest that 1–6 show different magnetic properties, and 2 and 6 display SMM-like behaviors.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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