MoO42−-templated Ln20Ni21heterometallic clusters with large low-field magnetic entropy

Author:

Yu Ya-Ting1,Bai Xu1,Wang Qin1,Wang Ji-Lei1ORCID,Xiang Xin-Ying1,Zhou Jiu-Lin1,Li Si-Man1,Xu Yan12ORCID

Affiliation:

1. College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, P. R. China

2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, P. R. China

Abstract

Two high-nuclearity transition-lanthanide (3d–4f) heterometallic clusters are acquired by incorporating MoO42−as an anionic template. A compound possesses a large magnetic entropy change value at 2 K for ΔH= 2 T is up to 23.85 J kg−1K−1.

Funder

National Natural Science Foundation of China

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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