A direct access to heterobimetallic complexes by roll-over cyclometallation-Reference-Cited by-同舟云学术

A direct access to heterobimetallic complexes by roll-over cyclometallation

Published:2017 Issue:88 Volume:53 Page:12016-12019
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Schön F.¹²³⁴,Leist M.¹²³⁴,Neuba A.⁵⁶⁷⁴,Lang J.¹²³⁴⁸,Braun C.⁹¹⁰¹¹⁴,Sun Y.¹²³⁴,Niedner-Schatteburg G.¹²³⁴⁸^ORCID,Bräse S.⁹¹⁰¹¹⁴¹²^ORCID,Thiel W. R.¹²³⁴^ORCID

Affiliation:

1. Fachbereich Chemie

2. TU Kaiserslautern

3. 67663 Kaiserslautern

4. Germany

5. Department Chemie

6. Universität Paderborn

7. 33098 Paderborn

8. Forschungszentrum OPTIMAS, Technische Universität Kaiserslautern

9. Institute of Organic Chemistry

10. Karlsruhe Institute of Technology

11. D-76131 Karlsruhe

12. Institute of Toxicology and Genetics

Abstract

Creation of a novel chelating site by roll-over cyclometallation opens up a new strategy for a rapid access to heterobimetallic complexes. Combinations of iridium(iii) with palladium(ii) or platinum(ii) have exemplarily been synthesized.

Funder

Deutsche Forschungsgemeinschaft

Konrad-Adenauer-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC07119A

Reference43 articles.

1. Nickel and Iron Pincer Complexes as Catalysts for the Reduction of Carbonyl Compounds

2. Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation

3. Transition metal-catalyzed cyclocarbonylation in organic synthesis

4. Organoiridium Complexes: Anticancer Agents and Catalysts

5. Anticancer cyclometalated complexes of platinum group metals and gold

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters;Journal of Organometallic Chemistry;2023-11

2. Probing Intermediates of Ion/Molecule Reactions by their Independent Gas‐Phase Synthesis and Fragmentation – The Thiomethoxymethyl Complexes [(bipy)M(CH₂SCH₃)]⁺ (M=Pt, Pd, Ni);Israel Journal of Chemistry;2023-05-10

3. Rhodium‐Catalyzed Annulations of 6‐Arylimidazothiazoles with Alkynes through Rollover Dual C−H Bond Activation Strategy;ChemistrySelect;2023-02-02

4. A rollover Ir(iii) complex of 2-(6-bromopyridin-2-yl)imidazo[1,2-a]pyridine;New Journal of Chemistry;2023

5. A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters;2023