A rollover Ir(<scp>iii</scp>) complex of 2-(6-bromopyridin-2-yl)imidazo[1,2-<i>a</i>]pyridine-Reference-Cited by-同舟云学术

A rollover Ir(iii) complex of 2-(6-bromopyridin-2-yl)imidazo[1,2-a]pyridine

Published:2023 Issue:12 Volume:47 Page:5625-5633
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Varela Yazmin¹,Ramírez-García Gonzalo²^ORCID,Jimenez-Halla J. Oscar C.³^ORCID,Segovia-Mendoza Mariana⁴,Prado-Garcia Heriberto⁵,Wrobel Katarzyna¹^ORCID,Wrobel Kazimierz¹^ORCID,Gutiérrez-Granados Silvia¹,Lemini Cristina⁴,Serrano Oracio¹^ORCID

Affiliation:

1. Departamento de Química, División de Ciencias Naturales y Exactas, Sede Pueblito de Rocha, Universidad de Guanajuato, Cerro de la Venada s/n, Pueblito de Rocha, C.P. 36040, Guanajuato, Gto, Mexico

2. Centro de Física Aplicada y Tecnología Avanzada, Biofunctional Nanomaterials Laboratory, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, C.P. 76230, Juriquilla, Qro, Mexico

3. Departamento de Química, División de Ciencias Naturales y Exactas, Sede Noria Alta, Universidad de Guanajuato, Noria Alta s/n, C.P. 36050, Guanajuato, Gto, Mexico

4. Departamento de Farmacología, Facultad de Medicina, Universidad Nacional Autónoma de México. Ciudad Universitaria, C.P. 04510, Ciudad de México, Mexico

5. Departamento de Enfermedades Crónico-Degenerativas, Laboratorio de Onco-Inmunobiología, Instituto Nacional de Enfermedades Respiratorias, “Ismael Cosio Villegas”, Calzada de Tlalpan 4502, Belisario Domínguez, Sección XVI, Tlalpan, C. P. 14080, Ciudad de México, Mexico

Abstract

Rollover iridacycle were easily obtained via a C–H bond activation on the remote position of the 2-(6-bromopyridin-2-yl)imidazo[1,2-a]pyridine ligand. DFT calculations suggest that C–H bond activation occurs during the complexation of the second ligand.

Funder

Consejo Nacional de Ciencia y Tecnología

Universidad de Guanajuato

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ06026D

Reference56 articles.

1. Producte der trocknen Destillation thierischer Materien

2. Synthesis of Pyridine and Dihydropyridine Derivatives by Regio- and Stereoselective Addition toN-Activated Pyridines

3. Bipyridine: The Most Widely Used Ligand. A Review of Molecules Comprising at Least Two 2,2‘-Bipyridine Units

4. “Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters;Journal of Organometallic Chemistry;2023-11

2. Zn(ii) and Cd(ii) pincer complexes bearing meta alkylated pyridinium amidates; synthesis & preliminary anticancer studies;New Journal of Chemistry;2023

3. A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters;2023