Allyl Ligand Reactivity in Tantalum(V) Compounds: Experimental and Computational Evidence for Allyl Transfer to the Formamidinate Ligand in fac-Ta(NMe2)3(η1-allyl)[iPrNC(H)NiPr] via a Metallo-Claisen Rearrangement-Reference-Cited by-同舟云学术

Allyl Ligand Reactivity in Tantalum(V) Compounds: Experimental and Computational Evidence for Allyl Transfer to the Formamidinate Ligand in fac-Ta(NMe2)3(η1-allyl)[iPrNC(H)NiPr] via a Metallo-Claisen Rearrangement

Published:2011-10-17 Issue:21 Volume:30 Page:5832-5843
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Huang Shih-Huang¹,Wang Xiaoping²,Nesterov Vladimir¹,Hrovat David A.¹³,Hall Michael B.⁴,Richmond Michael G.¹

Affiliation:

1. Department of Chemistry, University of North Texas, Denton, Texas 76203, United States

2. Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States

3. Center for Advanced Scientific Computing and Modeling, University of North Texas, Denton, Texas 76203, United States

4. Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om200683q

Reference73 articles.

1. Crystal and molecular structures of tert-butyltetrakis(dimethylamido)tantalum(V), bromo(p-tolyl)tris(dimethylamido)tantalum(V), and [(trimethylsilyl)methyl]tetrakis(N,N-dimethylcarbamato)tantalum(V). Evidence for stabilization of .sigma.-alkyl ligands by strongly .pi.-donating ligands in early transition metal chemistry

2. Synthesis of Tantalum(V) Amido Silyl Complexes and the Unexpected Formation of (Me2N)3Ta(η2-ONMe2)[OSi(SiMe3)3] from the Reaction of (Me2N)4Ta[Si(SiMe3)3] with O2

3. Synthesis and Characterization of Siloxy, Aminoxy, and Oxo Complexes from the Reaction of a Tantalum Amide Silyl Complex with Oxygen

4. Use of 1,1-Dimethylhydrazine in the Atomic Layer Deposition of Transition Metal Nitride Thin Films

5. Tantalum complexes with all nitrogen coordination sphere: mixed amido-, imido-, guanidinato complexes of tantalum and their thermal behaviour

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Evaluating Transition Metal Barrier Heights with the Latest Density Functional Theory Exchange–Correlation Functionals: The MOBH35 Benchmark Database;The Journal of Physical Chemistry A;2019-04-11

2. New azido-substituted tantalum compounds: syntheses and DFT examination of nitrogen-rich mono-, di-, and trinuclear tantalum(v) compounds;Dalton Transactions;2014

3. Synthesis and Structural Characterization of the Pentanuclear Tantalum Cluster Ta5(μ5-N)(μ3-N i Pr)2(μ2-N i Pr)6(η1-N i Pr)4(η1-NH i Pr)2 from the Reaction of Ta(NMe2)5 and i PrNH2: Unprecedented Formation of a Hinged-Butterfly Cluster Containing an Interstitial Nitride, Imido Groups, and Amido Groups;Journal of Chemical Crystallography;2012-06-27

4. Reaction mechanisms: pericyclic reactions;Annual Reports Section "B" (Organic Chemistry);2012

5. Vanadium, niobium and tantalum;Annual Reports Section "A" (Inorganic Chemistry);2012