Trapping of a 12-Valence-Electron Osmium Intermediate
Author:
Affiliation:
1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9002544
Reference39 articles.
1. Factors governing the equilibrium between metalalkyl, alkylidene and alkylidyne: MCX2R, XMCXR and X2MCR
2. C−C Coupling and C−H Bond Activation Reactions of Cyclopentadienyl−Osmium Compounds: The Rich and Varied Chemistry of Os(η5-C5H5)Cl(PiPr3)2 and Its Major Derivatives
3. Osmium–carbon double bonds: Formation and reactions
4. Reactions of an Osmium-Elongated Dihydrogen Complex with Terminal Alkynes: Formation of Novel Bifunctional Compounds with Amphoteric Nature
5. Reactions of Elongated Dihydrogen-Osmium Complexes Containing Orthometalated Ketones with Alkynes: Hydride-Vinylidene-π-Alkyne versus Hydride-Osmacyclopropene
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