Reactions of an Osmium-Elongated Dihydrogen Complex with Terminal Alkynes: Formation of Novel Bifunctional Compounds with Amphoteric Nature
Author:
Affiliation:
1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0200656
Reference76 articles.
1. Esteruelas, M. A.; López, A. M. Ruthenium- and Osmium-hydride compounds containing triisopropylphosphine as precursors for carbon−carbon and carbon−carbon-heteroatom coupling reactions.RecentAdvances in Hydride Chemistry; Elsevier: Amsterdam 2001; Chapter 7, pp 189−284.
2. Addition of CH3CO2H and HBF4 to Alkynyl Complexes of Ruthenium(II) and Osmium(II)
3. The Dihydride−Osmium(IV) Complex [OsH2(κ2-O2CCH3)(H2O)(PiPr3)2]BF4 as a Precursor for Carbon−Carbon Coupling Reactions
4. Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent
5. Hydride−Hydroxyosmacyclopropene versus Hydride−Hydroxycarbyne and Cyclic Hydroxycarbene: Influence of the Substituents at the C(OH) Carbon Atom of the Carbon Donor Ligand
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