Hydride−Hydroxyosmacyclopropene versus Hydride−Hydroxycarbyne and Cyclic Hydroxycarbene: Influence of the Substituents at the C(OH) Carbon Atom of the Carbon Donor Ligand-Reference-Cited by-同舟云学术

Hydride−Hydroxyosmacyclopropene versus Hydride−Hydroxycarbyne and Cyclic Hydroxycarbene: Influence of the Substituents at the C(OH) Carbon Atom of the Carbon Donor Ligand

Published:2000-05-01 Issue:11 Volume:19 Page:2184-2193
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Buil María L.¹,Esteruelas Miguel A.¹,García-Yebra Cristina¹,Gutiérrez-Puebla Enrique¹,Oliván Montserrat¹

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza- CSIC, 50009 Zaragoza, Spain, and Instituto de Ciencia de Materiales de Madrid, CSIC, Campus de Cantoblanco, 28049 Madrid, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9909542

Reference68 articles.

1. Dissociative Nucleophilic Substitution of η2-Olefin Complexes via a Novel η2-Vinyl Cation Intermediate

2. The mechanistic role of η2-vinyl complexes in metal-promoted alkyne oligomerisations. The crystal and molecular structures of [W{η5-C(CF3)C(CF3)C(CO2Me )C(CO2Me)C(CF3)C(CF3)SPri}(η5-C5H5)], [WF {η5-C(CF2)C(CF3)C( CO2Me)C( CO2Me)C(CF3)C(CF3)SPri}(η5-C5H5)], and [W{η4-C(CF3)C(CF3)C(Me)C(Me)SPri}(η2-CF3CCCF3)(η5-C5H5)]

3. Stabilisation of vinylic intermediate in the addition, cylisation, and oligomerisation reactions of alkynes by co-ordination to molybdenum and tungsten. The crystal and molecular structure of [W(SC6H4Me-p){η2-C(CF3)·C(CF3)PEt3}(η2-CF3CCCF3)(η-C5H5)] and [WCl{η2-C(CF3)·C(CF3)CNBut}(η2-CF3CCCF3)(η-C5H5)]

4. Electrophile-Promoted Carbon−Sulfur Bond Cleavage in η2-Thiophene Complexes of Pentaammineosmium(II)

5. Formation of novel η2-vinyl complexes by nucleophilic attack at co-ordinated hexafluorobut-2-yne; implications for the stereochemistry of addition and insertion reactions of co-ordinated acetylenes. Crystal and molecular structure of [Mo{SC5H4NC(CF3)·C(CF3)}-(CF3CCCF3)(η-C5H5)]

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