Stable group 8 metal porphyrin mono- and bis(dialkylcarbene) complexes: synthesis, characterization, and catalytic activity-Reference-Cited by-同舟云学术

Stable group 8 metal porphyrin mono- and bis(dialkylcarbene) complexes: synthesis, characterization, and catalytic activity

Published:2020 Issue:8 Volume:11 Page:2243-2259
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Hai-Xu¹²³⁴^ORCID,Wan Qingyun¹²³⁴^ORCID,Low Kam-Hung¹²³⁴^ORCID,Zhou Cong-Ying¹²³⁴⁵^ORCID,Huang Jie-Sheng¹²³⁴^ORCID,Zhang Jun-Long⁶⁷⁸⁹⁴^ORCID,Che Chi-Ming¹²³⁴¹⁰^ORCID

Affiliation:

1. State Key Laboratory of Synthetic Chemistry

2. Department of Chemistry

3. The University of Hong Kong

4. China

5. College of Chemistry and Materials Science

6. Beijing National Laboratory for Molecular Sciences

7. College of Chemistry and Molecular Engineering

8. Peking University

9. Beijing

10. HKU Shenzhen Institute of Research & Innovation

Abstract

We report the isolation, X-ray crystal structures, reactivity and DFT calculations of iron- and ruthenium-mono(dialkylcarbene) and osmium-bis(dialkylcarbene) porphyrins and diarylcarbene transfer/insertion reactions catalyzed by iron-mono(dialkylcarbene) porphyrin.

Funder

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05432D

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