Factors governing the equilibrium between metalalkyl, alkylidene and alkylidyne: MCX2R, XMCXR and X2MCR
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference14 articles.
1. Osmium Converts Terminal Olefins to Carbynes: α-Hydrogen Migration Redox Isomers with Reversed Stability for Ruthenium and for Osmium
2. Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynes
3. Hydrogen Migration and HCl Elimination Promoted by Metal-Centered Nucleophilic Attack on Osmium Hydrido−Carbynes
4. Coordinated carbenes from electron-rich olefins on RuHCl(PPr3i)2
5. A 14-Electron Ruthenium(II) Hydride, [RuH(CO)(PtBu2Me)2]BAr‘4 (Ar‘ = 3,5-(C6H3)(CF3)2): Synthesis, Structure, and Reactivity toward Alkenes and Oxygen Ligands
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2. Cyclohexane-Based Phosphinite Iridium Pincer Complexes: Synthesis, Characterization, Carbene Formation, and Catalytic Activity in Dehydrogenation Reactions;Organometallics;2017-01-31
3. Reactions of Osmium Carbyne Complexes OsCl3(≡CR)(PPh3)2 (R = CH═CPh2, CH2Ar) with Bromine and Hydrogen Peroxide;Organometallics;2017-01-18
4. Alkenylcarbyne Complexes Derived from the Reactions of OsXCl-(PPh3)3(X=H,Cl) with Propargyl Chloride and Phosphine Ligand-Controlled Transformation of Hydride-Carbyne to Carbene;Chinese Journal of Organic Chemistry;2017
5. Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance;Chemistry - A European Journal;2015-10-06
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