Aliphatic Carbon−Carbon Bond Cleavage Reactivity of a Mononuclear Ni(II) cis-β-Keto−Enolate Complex in the Presence of Base and O2: A Model Reaction for Acireductone Dioxygenase (ARD)
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322-0300, and Department of Chemistry, University of Utah, Salt Lake City, Utah 84112
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja056346x
Reference24 articles.
1. Acetylacetone-cleaving enzyme Dke1: a novel C-C-bond-cleaving enzyme from Acinetobacter johnsonii
2. Electronic Substituent Effects on the Cleavage Specificity of a Non-Heme Fe2+-Dependent β-Diketone Dioxygenase and Their Mechanistic Implications
3. Reaction Coordinate Analysis for β-Diketone Cleavage by the Non-Heme Fe2+-Dependent Dioxygenase Dke1
4. The Crystal Structure of a Quercetin 2,3-Dioxygenase from Bacillus subtilis Suggests Modulation of Enzyme Activity by a Change in the Metal Ion at the Active Site(s)
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