Formation of Ni(ii)-phenoxyl radical complexes by O2: a mechanistic insight into the reaction of Ni(ii)-phenol complexes with O2-Reference-Cited by-同舟云学术

Formation of Ni(ii)-phenoxyl radical complexes by O2: a mechanistic insight into the reaction of Ni(ii)-phenol complexes with O2

Published:2021 Issue:15 Volume:50 Page:5161-5170
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Suzuki Takashi¹²³⁴,Sato Akari¹²³⁴,Oshita Hiromi⁵⁶⁷⁴,Yajima Tatsuo⁸⁹¹⁰¹¹⁴^ORCID,Tani Fumito¹²¹³¹⁴⁴^ORCID,Abe Hitoshi¹²³⁴¹⁵^ORCID,Mieda-Higa Kaoru¹⁶¹⁷¹⁸⁴,Yanagisawa Sachiko¹⁶¹⁷¹⁸⁴,Ogura Takashi¹⁶¹⁷¹⁸⁴,Shimazaki Yuichi¹²³⁴^ORCID

Affiliation:

1. Graduate School of Science and Engineering

2. Ibaraki University

3. Mito 310-8512

4. Japan

5. Faculty of Chemistry of Functional Molecules

6. Konan University

7. Kobe 658-8501

8. Faculty of Chemistry

9. Materials and Bioengineering

10. Kansai University

11. Suita

12. Institute for Materials Chemistry and Engineering

13. Kyushu University

14. Fukuoka 819-0395

15. Institute of Materials Structure Science (IMSS)

16. Graduate School of Life Science

17. University of Hyogo

18. Kamigori

Abstract

The reaction of Ni(ii)-(phenol)(phenolate) complexes with O₂ gave the Ni(ii)-phenoxyl radical complexes assisted by CH₃OH. This reaction was concluded to undergo via the proton transfer–electron transfer type mechanism without redox of the Ni ion.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00105A

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5. Finding Intermediates in the O2 Activation Pathways of Non-Heme Iron Oxygenases

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