Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
2. Dipartimento di Chimica, Università di Parma, Viale delle Scienze 17/A, I-43100 Parma, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om400598m
Reference88 articles.
1. Reactive Hydroxo and Hydroxycarbyne Cyclopentadienyl Complexes. Proton Transfer and Oxidative Addition of O−H Bonds at Unsaturated Ditungsten Centers
2. Reactivity of the Carbyne Complexes [W2(μ-COR)(η5-C5H5)2(CO)2(μ-Ph2PCH2PPh2)]+ (R = H, Me) toward Diazomethane
3. Protonation Reactions on the Binuclear Complexes [W2Cp2(CO)n(μ-L2)] [L2 = Ph2PCH2PPh2, Me2PCH2PMe2; n = 2, 4]. Chemical Behavior of Their Hydrido and Hydroxycarbyne Derivatives
4. O-Protonation at a Neutral Ditungsten Carbonyl Dimer to Give a Stable Hydroxycarbyne Complex
5. Synthesis of the triply-bonded dimolybdenum anions [Mo2(η5-C5H5)2(μ-PA2)(μ-CO)2]− (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives
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3. Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study;European Journal of Inorganic Chemistry;2017-12-05
4. Carbyne–Carbyne Coupling and H-Shifts in Reactions of the Unsaturated Methoxy- and Hydroxycarbyne Complexes [Mo2Cp2(μ-COR)(μ-CPh)(μ-PCy2)]+ with CO and Isocyanides;Organometallics;2015-04-30
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