Protonation Reactions on the Binuclear Complexes [W2Cp2(CO)n(μ-L2)] [L2 = Ph2PCH2PPh2, Me2PCH2PMe2; n = 2, 4]. Chemical Behavior of Their Hydrido and Hydroxycarbyne Derivatives
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9806601
Reference47 articles.
1. Crabtree, R. H.Organometallic Chemistry of the Transition Metals, 2nd ed.; John Wiley and Sons: New York, 1994; Chapter 13, p 335.
2. Protonation of the metal-metal bond in [.mu.-(SCH3)Fe(CO)2L]2 complexes (L = P (CH3)3-x (C6H5)x). Experimental evidence of the variation of nucleophilicity of the metal-metal bond with donor properties of phosphorus ligands
3. Alkylation reactions of the CCO ligand in triruthenium carbonyl clusters. Synthesis and x-ray crystal structure of Ru3(CO)9(.mu.3-CO)[.mu.3-C:C(OCH3)CH3]
4. Reaction of the anionic acylmethylidyne cluster [Ru3(CO)9(.mu.3-CO)(.mu.3-CC(O)CH3)]- with carbon monoxide and hydrogen: reversible carbon-carbon and carbon-hydrogen bond forming reactions
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