Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−-Reference-Cited by-同舟云学术

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−

Published:2014 Issue:42 Volume:43 Page:16044-16055
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alvarez M. Angeles¹²³⁴,García M. Esther¹²³⁴,García-Vivó Daniel¹²³⁴^ORCID,Ruiz Miguel A.¹²³⁴,Vega M. Fernanda¹²³⁴

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM

2. Universidad de Oviedo

3. E-33071 Oviedo

4. Spain

Abstract

The title anion adds metal-based electrophiles at the ditungsten site, but its protonation gives mixtures of isomers with either bridging or terminal hydrides (W = WCp; P = PCy₂).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01915F

Reference58 articles.

1. F. A. Cotton and G.Wilkinson , Advanced Inorganic Chemistry , Wiley , New York , 5th edn, 1988 , ch. 22

2. Highly Reduced Metal Carbonyl Anions: Synthesis, Characterization, and Chemical Properties

3. Electrochemical investigation of the electron-poor/precise (n=5/6) complexes [Fe2(CO)n(μ-PR2)(μ-PR′2)] (n=5, RR′But; n=6, RR′Ph; RBut, R′Ph; RBut, R′Cy). EPR study of the radical anion [Fe2(μ-PBut2)2(CO)5]·.−

4. Synthesis and reactions of the [(.mu.-Ph2P)Fe2(CO)6]- anion

5. Transformations of a µ2-vinyl ligand at a dimanganese centre and the flexibility of µ2-acyl lignads; X-ray crystal structures of [(Ph2P)2N][Mn2(µ2-H){µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6], [Mn2{µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6(CNBut)2], and [Mn2{σ : η3-P(Ph)2CH : CH2}(CO)7(PEt3)]

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Nitrosyl derivatives of the halide-bridged complexes [M2Cp2(μ-X)(μ-P Bu2)(CO)2] (M = Mo, W; X = Cl, I).;Journal of Organometallic Chemistry;2024-05

2. Low-Valent Transition Metalate Anions in Synthesis, Small Molecule Activation, and Catalysis;Chemical Reviews;2024-02-14

3. Cyclic and Non-Cyclic Pi Complexes of Tungsten;Comprehensive Organometallic Chemistry IV;2022

4. A glimpse into the chemical reactivity of the unsaturated hydride [MoWCp2(H)(μ-PCy2)(CO)2];Journal of Organometallic Chemistry;2021-03

5. Hydride, alkyl and carbyne derivatives of the unsaturated heterometallic anion [MoWCp2(μ-PCy2)(μ-CO)2]−;Journal of Organometallic Chemistry;2019-08