Electrochemical investigation of the electron-poor/precise (n=5/6) complexes [Fe2(CO)n(μ-PR2)(μ-PR′2)] (n=5, RR′But; n=6, RR′Ph; RBut, R′Ph; RBut, R′Cy). EPR study of the radical anion [Fe2(μ-PBut2)2(CO)5]·.−-Reference-Cited by-同舟云学术

Electrochemical investigation of the electron-poor/precise (n=5/6) complexes [Fe2(CO)n(μ-PR2)(μ-PR′2)] (n=5, RR′But; n=6, RR′Ph; RBut, R′Ph; RBut, R′Cy). EPR study of the radical anion [Fe2(μ-PBut2)2(CO)5]·.−

Published:1994-03 Issue:1-2 Volume:217 Page:29-32
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

van der Linden J.G.M.,Heck J.,Walther B.,Böttcher H.-C.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference13 articles.

1. Structure and bonding of the coordinatively unsaturated complexes [Fe2(CO)5(.mu.-PR2)(.mu.-PR'2)](Fe = Fe) (R = R' = CMe3; R = Ph, R' = CMe3). Reaction of Na[Fe2(.mu.-CO)(CO)6(.mu.-PR2)] with R'2PCl, (R, R'= Ph, Cy, Me, CMe3)

2. Di-tert-butylphosphido versus diphenylphosphido as a bridging ligand in binuclear iron carbonyl complexes: synthesis and structural characterization of Fe2(CO)5(.mu.-P(tert-Bu)2)2 and Fe2(CO)6(.mu.-PPh2)(.mu.-P(tert-Bu)2)

3. Ein ungewöhnliches Paar Bis(phosphido)‐verbrückter Dieisencarbonylkomplexe: [Fe 2 (CO) n {μ‐P( t Bu) 2 }(μ‐PCy 2 )] ( n = 5 und 6)

4. Crystal structure of bis(.mu.-bis(trifluoromethyl)phosphido)-hexacarbonyldiiron, Fe2(CO)6[.mu.-P(CF3)2]2

5. Role of the metal-metal bond in transition-metal clusters. Phosphido-bridged diiron carbonyl complexes

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