Synthesis of the triply-bonded dimolybdenum anions [Mo2(η5-C5H5)2(μ-PA2)(μ-CO)2]− (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2009/DT/B909493H
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2. Electrochemical investigation of the electron-poor/precise (n=5/6) complexes [Fe2(CO)n(μ-PR2)(μ-PR′2)] (n=5, RR′But; n=6, RR′Ph; RBut, R′Ph; RBut, R′Cy). EPR study of the radical anion [Fe2(μ-PBut2)2(CO)5]·.−
3. Highly reduced organometallics. 9. Synthesis and characterization of the tetrasodium tetracarbonylmetalates(4-) of chromium, molybdenum, and tungsten, Na4M(CO)4: their reactions with weak acids to generate H2M2(CO)82-(M = Cr, Mo, and W)
4. Transformations of a µ2-vinyl ligand at a dimanganese centre and the flexibility of µ2-acyl lignads; X-ray crystal structures of [(Ph2P)2N][Mn2(µ2-H){µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6], [Mn2{µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6(CNBut)2], and [Mn2{σ : η3-P(Ph)2CH : CH2}(CO)7(PEt3)]
5. Synthesis and reactions of the [(.mu.-Ph2P)Fe2(CO)6]- anion
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