A Cluster Model Study of Contact Ion Pair Formation of t-BuCl in Aqueous Solution: Calculational Evidence for Nucleophilic Solvent Assistance in SN1 Reaction-Reference-Cited by-同舟云学术

A Cluster Model Study of Contact Ion Pair Formation of t-BuCl in Aqueous Solution: Calculational Evidence for Nucleophilic Solvent Assistance in SN1 Reaction

Published:1998-12-11 Issue:1 Volume:103 Page:190-196
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Okuno Yoshishige¹

Affiliation:

1. Research Center, Daicel Chemical Industries Ltd., 1239, Shinzaike, Aboshi-ku, Himeji, Hyogo 671-1234, Japan

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp983795t

Reference65 articles.

1. Photochemical and thermal denitrogenations of azoalkanes as mechanistic probes for the diradical intermediates involved in the di-.pi.-methane rearrangement of dibenzobarrelene

2. The SN2-SN1 spectrum. 3. Solvolyses of secondary and tertiary alkyl sulfonates in fluorinated alcohols. Further evidence for the SN2 (intermediate) mechanism

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