Do the solvolysis reactions of secondary substrates occur by the SN1 or SN2 mechanism: or something else?
Author:
Publisher
Springer Science and Business Media LLC
Subject
History,Biochemistry,General Chemistry
Link
http://link.springer.com/content/pdf/10.1007/s10698-011-9111-3.pdf
Reference40 articles.
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3. Allen, A.D., Kanagasabapathy, V.M., Tidwell, T.T.: Solvolysis of 1-Arylethyl Tosylates. Kinetic and stereochemical tests for solvent participation. J. Am. Chem. Soc. 107, 4513–4519 (1985)
4. Anslyn, E.V., Dougherty, D.A.: Modern physical organic chemistry. University Science Books, Sausalito, CA (2006)
5. Bentley, T.W., Bowen, C.T., Morten, D.H., Schleyer, P., Von, R.: The SN2-SN1 Spectrum. 3. Solvolyses of secondary and tertiary alkyl sulfonates in fluorinated alcohols. Further evidence for the SN2 (Intermediate) mechanism. J. Am. Chem. Soc. 103, 5466–5475 (1981)
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