A solvent-catalyzed four-molecular two-path solvolysis mechanism of t-butyl chloride or bromide in water or alcohol derived by density functional theory calculation and confirmed by high-resolution electrospray ionization-mass spectrometry-Reference-Cited by-同舟云学术

A solvent-catalyzed four-molecular two-path solvolysis mechanism of t-butyl chloride or bromide in water or alcohol derived by density functional theory calculation and confirmed by high-resolution electrospray ionization-mass spectrometry

Published:2020-02-13 Issue:2 Volume:129 Page:583-612
ISSN:1878-5190
Container-title:Reaction Kinetics, Mechanisms and Catalysis
language:en
Short-container-title:Reac Kinet Mech Cat

Author:

Shi Hongchang

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry,Catalysis

Link

http://link.springer.com/content/pdf/10.1007/s11144-020-01723-w.pdf

Reference50 articles.

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3. Hughes ED, Ingold CK (1937) Reaction kinetics and the Walden inversion. Part I. Homogeneous hydrolysis and alcoholysis of β-n-octyl halides. J Chem Soc 1937:1196–1201

4. Cowdrey WA, Hughes ED, Ingold CK (1937) Reaction kinetics and the Walden inversion. Part III. Homogeneous hydrolysis and alcoholysis of α-bromopropionic acid, its ester and anion. J Chem Soc 1937:1208–1236

5. Cowdrey WA, Hughes ED, Ingold CK, Scott S, Masterman S (1937) Reaction kinetics and the Walden inversion. Part VI. Relation of steric orientation to mechanism in substitutions involving halogen atoms and simple or substituted hydroxyl groups. J Chem Soc 1937:1252–1271

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