Steric Control of Lanthanide Coordination Environment: (TpMe2)2Sm(C⋮CPh), a Monomeric, Base-Free Lanthanide Alkynide Complex, and Its Thermally Induced Transformation to (TpMe2){HB(Me2pz)2(C⋮CPh)}Sm(Me2pz)-Reference-Cited by-同舟云学术

Steric Control of Lanthanide Coordination Environment: (TpMe2)2Sm(C⋮CPh), a Monomeric, Base-Free Lanthanide Alkynide Complex, and Its Thermally Induced Transformation to (TpMe2){HB(Me2pz)2(C⋮CPh)}Sm(Me2pz)

Published:2000-04-08 Issue:10 Volume:19 Page:1814-1816
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Lin Guanyang¹,McDonald Robert¹,Takats Josef¹

Affiliation:

1. Department of Chemistry and X-ray Crystallography Laboratory, University of Alberta, Edmonton, Alberta, Canada T6G 2G2

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9906518

Reference29 articles.

1. Catalytic oligomerization of terminal alkynes by lanthanide carbyls (.eta.5-C5Me5)2LnCH(SiMe3)2 (Ln = Y, La, Ce)

2. Reactions of yttrium-carbon bonds with active hydrogen-containing molecules. A useful synthetic method for permethylyttrocene derivatives

3. Insertion and C−H Bond Activation of Unsaturated Substrates by Bis(benzamidinato)yttrium Alkyl, [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(SiMe3)2), and Hydrido, {[PhC(NSiMe3)2]2Y(μ-H)}2, Compounds

4. Reversible Yttrium Alkynide Coupling Supported by DAC (Deprotonated 4,13-Diaza-18-crown-6) Ligation

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