Insertion and C−H Bond Activation of Unsaturated Substrates by Bis(benzamidinato)yttrium Alkyl, [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(SiMe3)2), and Hydrido, {[PhC(NSiMe3)2]2Y(μ-H)}2, Compounds
Author:
Affiliation:
1. Groningen Center for Catalysis and Synthesis, Department of Chemistry, Nijenborgh 4, 9747 AG Groningen, The Netherlands
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9508142
Reference72 articles.
1. Ancillary Ligand Effects in Organoyttrium Chemistry: Synthesis, Characterization, and Electronic Structure of Bis(benzamidinato)yttrium Compounds
2. Methane exchange reactions of lanthanide and early-transition-metal methyl complexes
3. Facile C–H activation by lutetium–methyl and lutetium–hydride complexes
4. Organolanthanide and organoyttrium hydride chemistry. 5. Improved synthesis of [(C5H4R)2YH(THF)]2 complexes and their reactivity with alkenes, alkynes, 1,2-propadiene, nitriles, and pyridine, including structural characterization of an alkylideneamido product
5. Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes
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