Assembly of metallo-macrocycles through reductive C–C coupling of alkylnitriles by an Mg–Mg-bonded compound-Reference-Cited by-同舟云学术

Assembly of metallo-macrocycles through reductive C–C coupling of alkylnitriles by an Mg–Mg-bonded compound

Published:2022 Issue:11 Volume:51 Page:4394-4399
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xue Yujie¹,Wang Jijiang¹,Shi Yalei¹,Xu Wenhua¹^ORCID,Zhao Yanxia¹^ORCID,Wu Biao²^ORCID,Yang Xiao-Juan¹²^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, China

2. Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

Abstract

The dimagnesium(i) compound readily activates n-alkylnitriles to afford unique trinuclear magnesium macrocyclic complexes, [LMg(μ-{(NC–C(R)C(CH2R)–NH})]3[K3(Solv)6], through a reductive α-H deprotonation, C–C coupling, and 1,3-H shift.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00181K

Reference55 articles.

1. Catalytic reactions involving the cleavage of carbon–cyano and carbon–carbon triple bonds

2. Additions to Metal-Activated Organonitriles