Synthesis and Structure Diversity of Half‐Sandwich Rare Earth Dialkynyl Complexes
Author:
Affiliation:
1. Advanced Catalysis Research Group RIKEN Center for Sustainable Resource Science 2-1 Hirosawa Wako, Saitama 351-0198 Japan
2. Organometallic Chemistry Laboratory RIKEN Cluster for Pioneering Research 2-1 Hirosawa Wako, Saitama 351-0198 Japan
Publisher
Wiley
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Drug Discovery,Biochemistry,Catalysis
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/hlca.202100197
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2. Investigation of organolanthanide-based carbon-carbon bond formation: synthesis, structure, and coupling reactivity of organolanthanide alkynide complexes, including the unusual structures of the trienediyl complex [(C5Me5)2Sm]2[.mu.-.eta.2:.eta.2-Ph(CH2)2C:C:C:C-(CH2)2Ph] and the unsolvated alkynide [(C5Me5)2Sm(C.tplbond.CCMe3)]2
3. Novel Z-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Half-Metallocene Complexes
4. Neutral and Cationic Alkyl and Alkynyl Complexes of Lanthanum: Synthesis, Stability, and Cis-Selective Linear Alkyne Dimerization
5. Scandium, Yttrium, and Lanthanum Benzyl and Alkynyl Complexes with theN-(2-Pyrrolidin-1-ylethyl)-1,4-diazepan-6-amido Ligand: Synthesis, Characterization, andZ-Selective Catalytic Linear Dimerization of Phenylacetylenes
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