Stereoselective Synthesis of Stereotriad Subunits of Polyketides through Additions of Nonracemic Allenylsilanes to (R)- and (S)-2-Methyl-3-oxygenated Propanals
Author:
Affiliation:
1. Department of Chemistry, University of Virginia Charlottesville, Virginia 22904
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo991543y
Reference11 articles.
1. Synthesis of enantioenriched homopropargylic alcohols through diastereoselective SE' additions of chiral allenylstannanes to aldehydes
2. Synthesis of Chiral Enantioenriched Homopropargylic Alcohols from Propargylic Mesylates via Chiral Allenylzinc Intermediates
3. Formation of Transient Chiral Allenylindium Reagents from Enantioenriched Propargylic Mesylates through Oxidative Transmetalation. Applications to the Synthesis of Enantioenriched Homopropargylic Alcohols
4. Diastereoselective and Enantioselective Synthesis of Homopropargyl and Allenylcarbinols from Nonracemic Propargyl Mesylates via the Derived Allenyl and Propargyl Trichlorosilanes
5. Scope and stereochemical course of the addition of (trimethylsilyl)allenes to ketones and aldehydes. A regiocontrolled synthesis of homopropargylic alcohols
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