Copper-catalyzed silylation of propargyl carbonates: a general entry to allenylsilanes-Reference-Cited by-同舟云学术

Copper-catalyzed silylation of propargyl carbonates: a general entry to allenylsilanes

Published:2023 Issue:14 Volume:10 Page:3598-3602
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang He¹²,Jiang Linjuan³,Yang Mei¹²,Liu Yuanhong¹²^ORCID

Affiliation:

1. Division of Molecular Catalysis and Synthesis, Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou 450001, P. R. China

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, People's Republic of China

3. School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 20023, P. R. China

Abstract

A copper-catalyzed silylation of propargyl carbonates with silylboranes affords structurally diverse allenylsilanes including tri- or tetra-substituted and 1,1- or 1,3-disubstituted allenylsilanes.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00371J

Reference37 articles.

1. (Trimethylsilyl)allenes as propargylic anion equivalents: synthesis of homopropargylic alcohols and ethers

2. Scope and stereochemical course of the addition of (trimethylsilyl)allenes to ketones and aldehydes. A regiocontrolled synthesis of homopropargylic alcohols