Diastereoselective and Enantioselective Synthesis of Homopropargyl and Allenylcarbinols from Nonracemic Propargyl Mesylates via the Derived Allenyl and Propargyl Trichlorosilanes
Author:
Affiliation:
1. Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo971853l
Reference10 articles.
1. Diastereo- and enantioselective synthesis of allenylcarbinols through SE2' addition of transient nonracemic propargylic stannanes to aldehydes.
2. Synthesis of syn,syn; anti,syn; syn,anti; and anti,anti Stereotriads from a Single Pair of Enantiomeric Reagents
3. Synthesis of a C22-34 Subunit of the Immunosuppressant FK-506
4. Facile and Highly Stereoselective Synthesis of Homoallylic Alcohols Using Organosilicon Intermediates
5. Selective Formation of Propargylsilanes and Allenylsilanes and Their Reactions with Aldehydes for the Preparation of Homopropargylic and Allenic Alcohols
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