Stereoselective Oxidative Additions of Iodoalkanes and Activated Alkynes to a Sulfido-Bridged Heterotrinuclear Early−Late (TiIr2) Complex
Author:
Affiliation:
1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic034278e
Reference61 articles.
1. Metal-metal bond formation in the oxidative addition to dinuclear gold(I) species. Implications from dinuclear and trinuclear gold chemistry for the oxidative addition process generally
2. Diverse Reactivity of Alkynes with the Binuclear Methyl and Incipient Methyl Complexes [RhIr(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3] and [Ir2H(CO)3(μ-CH2)(Ph2PCH2PPh2)2][CF3SO3]
3. Pyrazolyl-Bridged Iridium Dimers. 16.1 The Atropisomeric (C2) System [Ir(CO)(PPh3)(μ-pz)]2. Synthesis of Homologous Diastereomeric Complexes That Undergo Slow Stereomutation by Ring Inversion of the Bridging Framework: Mechanistic Implications for Bimetallic Substrate Activation
4. Co-operativity effects between adjacent metal sites—kinetics of methyl iodide addition to pyrazolyl-bridged iridium dimers: argument for a concerted mechanism in the reversible two-fragment, two-centre oxidative addition to the cyclo-octa-1,5-diene di-iridium(I) complex [Ir(COD)(µ-pz)]2
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