Diverse Reactivity of Alkynes with the Binuclear Methyl and Incipient Methyl Complexes [RhIr(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3] and [Ir2H(CO)3(μ-CH2)(Ph2PCH2PPh2)2][CF3SO3]-Reference-Cited by-同舟云学术

Diverse Reactivity of Alkynes with the Binuclear Methyl and Incipient Methyl Complexes [RhIr(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3] and [Ir2H(CO)3(μ-CH2)(Ph2PCH2PPh2)2][CF3SO3]

Published:1996-01-23 Issue:2 Volume:15 Page:506-520
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Antwi-Nsiah Frederick H.¹,Oke Okemona¹,Cowie Martin¹

Affiliation:

1. Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9505118

Reference120 articles.

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3. Vinylidene transition-metal complexes. Part 13. The reactivity of [IrH5(PPri3)2] and [IrH2Cl(PPri3)2] toward Alk-1-ynes: synthesis of four-, five- and six-co-ordinate iridium complexes containing alkynyl, vinyl and vinylidene ligands

4. Metal-hydride alkynyl .fwdarw. metal-vinylidene rearrangements occurring in both solid state and solution. Role of the 1-alkyne substituent in determining the relative stability of .pi.-alkyne, hydride alkynyl, and vinylidene forms at cobalt

5. Bridged hydrocarbyl or hydrocarbon binuclear transition metal complexes: classification, structures, and chemistry

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