Pyrazolyl-Bridged Iridium Dimers. 16.1 The Atropisomeric (C2) System [Ir(CO)(PPh3)(μ-pz)]2. Synthesis of Homologous Diastereomeric Complexes That Undergo Slow Stereomutation by Ring Inversion of the Bridging Framework: Mechanistic Implications for Bimetallic Substrate Activation
Author:
Affiliation:
1. Department of Chemistry, University of Victoria, British Columbia, Canada V8W 2Y2
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9601864
Reference13 articles.
1. Molecular mechanics and NOE investigations of the solution structures of intermediates in the [rhodium(chiral bisphosphine)]+-catalyzed hydrogenation of prochiral enamides
2. Oxidative Addition Mechanisms of a Four-Coordinate Rhodium (I) Macrocycle
3. Co-operativity effects between adjacent metal sites—kinetics of methyl iodide addition to pyrazolyl-bridged iridium dimers: argument for a concerted mechanism in the reversible two-fragment, two-centre oxidative addition to the cyclo-octa-1,5-diene di-iridium(I) complex [Ir(COD)(µ-pz)]2
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